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Conjugate-base-stabilized bronsted acids as asymmetric catalysts: Enantioselective povarov reactions with secondary aromatic amines
Caught in the act: A new concept for asymmetric Bronsted acid catalysis is presented. Compounds containing an acidic functionality in addition to an anion recognition site act as powerful conjugate-base-stabilized Bronsted acid catalysts. This strategy was applied to the first catalytic enantioselective three-component Povarov reaction of indoline and other secondary aromatic amines (see scheme; M.S.=molecular sieves). Copyright
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Reference：
Pyridazine – Wikipedia,
Pyridazine | C4H4N949 – PubChem