Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 88-17-5, Name is 2-(Trifluoromethyl)aniline, SMILES is NC1=CC=CC=C1C(F)(F)F, belongs to pyridazines compound. In a document, author is Rodriguez-Jimenez, Santiago, introduce the new discover, Computed Properties of C7H6F3N.
Predictable Electronic Tuning By Choice of Azine Substituent in Five Iron(II) Triazoles: Redox Properties and DFT Calculations
Five new mononuclear iron(II) tris-ligand complexes, and four solvatomorphs, have been made from the azine-substituted 1,2,4-triazole ligands (L-azine): [Fe-II(L-pyridazine)(3)](BF4)(2) (1), [Fe-II(L-pyrazine)(3)](BF4)(2) (2), [Fe-II(L-pyridine)(3)](BF4)(2) (3), [Fe-II(L-2pyrimidine)(3)](BF4)(2) (4), and [Fe-II(L-4pyrimidine)(3)](BF4)(2) (5). Single-crystal XRD and solid-state magnetometry reveal that all of them are low-spin (LS) iron(II), except for solvatomorph 54H(2)O. Evans method NMR studies in CD2Cl2, (CD3)(2)CO and CD3CN show that all are LS in these solvents, except 5 in CD2Cl2 (consistent with L-4pyrimidine imposing the weakest field). Cyclic voltammetry in CH3CN vs. Ag/0.01m AgNO3 reveals an, at best quasi-reversible, Fe-III/II redox process, with E-pa increasing from 0.69 to 0.99V as the azine changes: pyridine< pyridazine<2-pyrimidine<4-pyrimidine< pyrazine. The observed E-pa values correlate linearly with the DFT calculated HOMO energies for the LS complexes. The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 88-17-5 is helpful to your research. Computed Properties of C7H6F3N.
Reference:
Pyridazine – Wikipedia,
,Pyridazine | C4H4N2 – PubChem