Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Liu Qiang, once mentioned the application of 19430-93-4, Name is 3,3,4,4,5,5,6,6,6-Nonafluorohex-1-ene, molecular formula is C6H3F9, molecular weight is 246.0737, MDL number is MFCD00042338, category is pyridazines. Now introduce a scientific discovery about this category, SDS of cas: 19430-93-4.
Metal-Free Direct C-H beta-Carbonyl Alkylation of Heteroarenes with Cyclopropanols Mediated by K2S2O8
Direct C-H beta-carbonyl alkylation of heteroarenes under metal-, acid- and photo-catalyst free conditions has been achieved. A wide scope of substrates, such as various substituted quinolines and isoquinolines, pyridines, pyridazine, benzo[d]thiazole and phenanthroline, underwent the beta-carbonyl alkylation efficiently via K2S2O8-mediated ring-opening of cyclopropanols. The corresponding beta-heteroarylated ketones were obtained in moderate to excellent yields and gram-scale experiments further demonstrated the practicality of this synthetic protocol. The readily available reagents, mild and environmentally benign conditions make the method extremely attractive. The reaction mechanism is also proposed.
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Reference:
Pyridazine – Wikipedia,
,Pyridazine | C4H4N2 – PubChem