One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time. 920-66-1, Name is 1,1,1,3,3,3-Hexafluoropropan-2-ol, formurla is C3H2F6O. In a document, author is Soderstrom, Marcus, introducing its new discovery. Formula: C3H2F6O.
BF3 center dot SMe2 for Thiomethylation, Nitro Reduction and Tandem Reduction/SMe Insertion of Nitrogen Heterocycles
Herein, a general, solvent-free and straightforward thiomethylation of electron deficient heterocycles using BF3 center dot SMe2 as a dual thiomethyl source and Lewis acidic activator is presented. A range of heterocycles including pyrimidine, pyrazine, pyridazine, thiazole and purine derivatives were successfully substituted using this method. An unexpected reductive property of BF3 center dot SMe2 towards nitropyridines was also discovered including an intriguing tandem reduction/SMe insertion process in certain substrates. Notable features of the present work include its convenience and use of a non-malodorous reagent while the discovery of novel chemical transformations using BF3 center dot SMe2 provides fundamental new insights into the reactivity of this commonly employed reagent.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 920-66-1 help many people in the next few years. Formula: C3H2F6O.
Reference:
Pyridazine – Wikipedia,
,Pyridazine | C4H4N2 – PubChem