Gao, Run-Duo; Xu, Qing-Long; Dai, Li-Xin; You, Shu-Li published the article 《Pd-catalyzed cascade allylic alkylation and dearomatization reactions of indoles with vinyloxirane》. Keywords: tetrahydrocarboline preparation; indolylmethyl malonate vinyloxirane cascade ring opening allylic alkylation palladium; spiroindolenine preparation diastereoselective; indolylethyl malonate vinyloxirane cascade ring opening allylic dearomatization palladium.They researched the compound: 5-Methoxy-1H-indole-2-carbaldehyde( cas:21778-81-4 ).Recommanded Product: 5-Methoxy-1H-indole-2-carbaldehyde. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:21778-81-4) here.
A palladium-catalyzed cascade allylic alkylation reaction of di-Me malonate tethered indoles with vinyloxirane was developed through intramol. nucleophilic ring-opening of vinyloxirane followed by subsequent intramol. Friedel-Crafts type allylic alkylation or allylic dearomatization. This protocol provided an efficient method to synthesize structurally diverse tetrahydrocarbolines e.g., I, and spiroindolenine derivatives e.g., II, under mild conditions.
This literature about this compound(21778-81-4)Recommanded Product: 5-Methoxy-1H-indole-2-carbaldehydehas given us a lot of inspiration, and I hope that the research on this compound(5-Methoxy-1H-indole-2-carbaldehyde) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Pyridazine – Wikipedia,
Pyridazine | C4H4N2 – PubChem