The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 2605-67-6, Name is Methyl 2-(triphenylphosphoranylidene)acetate, SMILES is C3=C([P](C1=CC=CC=C1)(C2=CC=CC=C2)=CC(OC)=O)C=CC=C3, in an article , author is Adiraju, Venkata A. K., once mentioned of 2605-67-6, Computed Properties of C21H19O2P.
Isomer Dependence on the Reactivity of Diazenes with Pentaphenylborole
Reactions of the anti-aromatic pentaphenylborole with diazenes indicate that both the substitution and the isomer influence the reaction outcome. With respect to trans isomers, azobenzene underwent coordination and C-H addition across the diene of the borole, and 2′, 6′-dimethylazobenzene furnished a fused tricyclic system. Under photolytic conditions, both of the aforementioned diazenes generate the first 1,3,2-diazaborepin heterocycles, rationalized through reactivity with the cis isomers. This notion is corroborated by the reaction of pentaphenylborolewith benzo[c]-cinnoline, the tethered variant of azobenzene, that only exists as the cis conformer as the corresponding 1,3,2-diazaborepin was produced regardless if the reaction is conducted in the dark or light. The more aromatic pyridazine proved to be less reactive, forming a resilient adduct.
Interested yet? Read on for other articles about 2605-67-6, you can contact me at any time and look forward to more communication. Computed Properties of C21H19O2P.
Reference:
Pyridazine – Wikipedia,
,Pyridazine | C4H4N2 – PubChem