Chemistry, like all the natural sciences, begins with the direct observation of nature¡ª in this case, of matter.2231-57-4, Name is Carbonothioic dihydrazide, SMILES is NNC(NN)=S, belongs to pyridazines compound. In a document, author is Ghosh, Biswa Nath, introduce the new discover, Recommanded Product: Carbonothioic dihydrazide.
Mononuclear and dinuclear trimethylplatinum(IV) iodide complexes of 3-substituted pyridines
Reaction of tetrameric trimethylplatinum(IV) iodide with an excess of 3-substituted pyridines in chloroform afforded mononuclear complexes, [PtMe3L2I] (L = 3-CNpy, 3-Brpy, 3-MeOpy, 3-Mepy and 3-Etpy). The complexes were characterized by H-1 NMR, CHN analysis and X-ray single crystal structure analysis. The mononuclear complexes undergo reaction with trimethylplatinum(IV) iodide in chloroform to form the corresponding dinuclear forms (both syn and anti). A comparison of both the mononuclear and dinuclear forms in solution for a particular pyridine substituent has been studied in detail with the help of H-1 NMR spectroscopy, ably supported by DFT computational studies. The investigation further shows the influence of the pyridine substituent on controlling the mode of the reaction. The crystal structures of two dinuclear complexes, syn-[PtMe3(3-CNpy)I](2) and anti-[PtMe3(3-Brpy)I](2), have also been described here.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 2231-57-4 is helpful to your research. Recommanded Product: Carbonothioic dihydrazide.
Reference:
Pyridazine – Wikipedia,
,Pyridazine | C4H4N2 – PubChem