Some scientific research about 932-22-9

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Reference of 932-22-9, Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. 932-22-9, Name is 4,5-Dichloro-3(2H)-pyridazinone,introducing its new discovery.

Chemistry of Phenoxathiins and Isosterically Related Heterocycles. XXIV. Synthesis and Characterization by 13C-NMR Spectroscopy of Isomeric Benzoxathiinopyridazinones: 1-Oxo-1,2-dihydro-2,3-diazaphenoxathiin and 4-Oxo-3,4-dihydro-diazaphenoxathiin. The First Observation of a Smiles …

Condensation of a disodium salt of o-mercaptophenol with 4,5-dichloro-6(1H)-pyridazinone in N,N-dimethylformamide has been observed to lead to the formation of both possible isomeric benzoxathiinopyridazinones.The separation of these isomers, 1-oxo-1,2-dihydro-2,3-diazaphenoxathiin and 4-oxo-3,4–dihydro-2,3-diazaphenoxathiin and their characterization by 13C-nmr spectroscopy is described.Mechanisms to account for the formation of both isomers are discussed, the most probable mechanism involving a Smiles rearrangement of the phenolate sulfide intermediate formed by the initial displacement of the 4-chloro substituent, providing a specie analogous to a beta-halovinylogous ketone.

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Pyridazine – Wikipedia,
Pyridazine | C4H4N2373 – PubChem