Downstream synthetic route of 1211587-01-7

1211587-01-7 5-Chloropyridazine-3-carboxylic acid 19792063, apyridazine compound, is more and more widely used in various fields.

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.1211587-01-7,5-Chloropyridazine-3-carboxylic acid,as a common compound, the synthetic route is as follows.

The carboxylic acid (243 mg, 1.53 mmol) was dissolved in ~15 mL of ethanol and treated with 24 mg (0.2 mmol) of dimethylaminopyridine (DMAP) followed by 324 mg (1.69 mmol) 1-(3-dimethylaminopropyl-3-ethylcarbodiimide hydrochloride (EDCl). The reaction was stirred at ambient temperature for 4 hours and then worked up by the procedure described in Example 166A. The crude product was purified by flash chromatography on silica gel to give 150 mg (52%) of the title compound as a white crystalline solid. 1 H NMR (CDCl3, 300 MHz) delta 1.45 (t, 3H), 4.55 (q, 2H), 7.65 (d, 1H), 8.15 (d, 1H). MS (DCl/NH3) m/e 187/189 (M+H)+, 204/206 (M+H+NH3)+., 1211587-01-7

1211587-01-7 5-Chloropyridazine-3-carboxylic acid 19792063, apyridazine compound, is more and more widely used in various fields.

Reference£º
Patent; Abbott Laboratories; US5250548; (1993); A;,
Pyridazine – Wikipedia
Pyridazine | C4H4N2 – PubChem